I would believe what Eod stated as being the first. However, I believe that it could of been from either: ARGES (Austria), DIEL (Germany, West), or maybe even another Country I haven't heard before. But I guess I would agree with Diehl. IMHO, they make the best out there to the point that they sold SEAL Team 6 some M-DN 11 H/G's. Unknown amout though. If you ever get to see the first time the Taliban tried to kill Karhzid (?) a while back, the SEALS (Team 6) where on their turn at protecting Karhzid when hell broke loose. The team had a memeber dressed up like a local. He is shown in the photograph to have at least one in his belt.
Now, I will try and finish the list of grenades that use Plastic/Polymer along with the "Dual ignition source's": SHG 60 DNW H/G (Austria), Sp1HGr 80/DNW H/G (Austria), Type HG77 (Austria), Type HG78 H/G (Austria), Type HG84 H/G (Austria), Type HG85 H/G (Austria), Type HG86 "Mini" H/G (Austria), Glock SHG H/G (Austria), PRB NR 423 H/G (Belgium), Luchaire LU 213&217 A-APERS-FRAG H/G (France/I believe these may be polymer, do not know for sure?), Losfeld H/G and the Losfeld Multi-Purpose AP H/G This system is using this grenade and attaching it onto a bullet trap tail unit. It then has three modes;Delay, Impact, and Nominal Delay of 5 seconds) France), M-DN 11 H/G (Germany, West), M-DN 21 H/G (Germany, West), M-DN 31 H/G (Germany, West), M-DN 61 H/G (Germany, West), DM 51 Off. & Def.; my favorite(Germany, West), Elviemek EM01 H/G (Greece), Elviemek EM02 H/G (Greece), MU-50/G MISAR H/G (Italy), OD/82 H/G (Italy), NR20 C1 Eurometaal H/G Somebody here has one of these? (Netherlands), M313 H/G (Portugal), M314 H/G (Portugal), M5 & M6 & MB-8 R-41 H/G's are all from (Spain), M75 H/G supposedly developed by Bulgaria, anybody? It is used in Bulgaria, Yugoslavia (Former), Russia, China, Chetchnya, and others probably too numerous to name. Also, there is the M217 fuse for some Hand Grenades that were in our inventory (USA). It is an "Impact" fuse by nature with a built in back up delay of 7 seconds should the grenade not hit anything hard on the way out. However, this fuse can be temperature sensitive, especially in +52C and below -40C.
Paul, sorry if I went with the ones you have. Along with the others too. Thanks Fragman!