I too have seen very old CN/DM canisters that should of been gone a very long time ago. I believe that DM was just too dangerous to keep producing it and especially using it. DM is just bad juju. It can and sometimes did kill people in the 30's-60's. Liability for use was something no department wanted to face back then, especially when it had a track record of people dying with high doses. I was told many years ago, circa the 1980 that they were in stock in the armory in Columbus, Ohio by the Army and/or the NG. This was supposedly a rumor I found out only later on.
If there were any left and they were properly stored, I believe the expiration was far passed it's usefulness. The only way to get rid of it was to burn it in a very hot, very large, incinerater where they dispose of Nerve agents, and other lethal munitions. I am not sure where one is though? In the Army's FM 19 - 15 Civil Disorders (November, 1985) they seem to use CS in both liquid and dry forms against rioters. They also mention a lot about using the the M33A1 which looks like an old vintage flamethrower. They also talk about the use of the M5 disperser from helicopters. No DM is mentioned anywhere in the text that I could fine. Now they do mention the use of firearms (the Army calls it: "Extreme Force Options"). Basically the Army/NG is having things going bad to worse and they are loosing ground from a very hostile crowd. This option consists of the following: Shotguns using either No. 7 1/2 to No. 9 "Birdshot" and all they way up to 00 buck and this does not mean using any "skip firing" either. Rifles, using either 5.56 x 45mm or 7.62 x 51mm. Machineguns just like the use of the rifle ammo. There will be NO use of any ammunition larger than 7.62. This means no .50cals, 20mm's, and no larger. The use of the M234 "ring-foil" attachment on the end of an M16/AR-15 series of rifles using the bayonet lug, flashider, and the front sight post as to where it mounts on these rifles. Only the use of "Blank" ammunition is advised. Everything stated above as far as the EFO operations are concerned, they will be used by the Army's SRT's and certain select individuals within the line itself.
No DM mentioned.
In an FBI study released to the IACP on 3 April 1967 entitled: "PREVENTION AND CONTROL OF MOBS AND RIOTS" no mention of using DM is in there. Just Hoses, Horses, Dogs, and Fire Hydrants. Yes, Fire Hydrants. Riots typically break out when the ambient temperature goes over the 90+ degree mark, in the hottest months of the Summer; usually June and July. They can also form during Spring, Fall, or even in the winter these are the exceptions rather than the norm. I believe Philidelphia has used this method many, many times since the 1960's. When tempers flair along with intermittant black outs or brown outs and people cannot find somwhere cool, hot heads do prevail. This is when the Fire Department along with a Police Unit go to very poor neighborhoods and open up the hydrants using special devices to make it fun for kids and adults alike. It really works unless their is a determined hostile crowd that its sole purpose is to disrupt the city because of a Police Shooting of a minority.
This is all I have on Riots, Civil Disorders, Mobs, and Inserections.
For more info on what the DM and CN canisters looked like I suggest you get a copy of Darryl Lynn's book entitled: "The Grenade Recognition Manual, Volume 1". Mr. Lynn is a member here too.
The subject on everything to do with DM, DM/CN and there use in Riots, etc., ect. are possibly exhausted on this thread? IMHO, I have given you TMI on riots and maybe not enough on the DM chemical. Although, I believe you have been given about all the info that we know on Diphenyl amine-chlorarsine. The definition of the active ingrediant in DM is Chloarsine and is stated in this paragraph from "wiki".
Arsine is the chemical
compound with the
formula AsH[SUB]3[/SUB]. This flammable,
pyrophoric, and highly toxic gas is one of the simplest compounds of
arsenic. Despite its lethality, it finds applications in the semiconductor industry and for the synthesis of
organoarsenic compounds